Silicon Mediated Transformations Of Functional Groups

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Silicon-mediated Transformations of Functional Groups :

Science

Author - Helmut Vorbrueggen
Publisher - John Wiley & Sons
Pages - 378
ISBN - 3527605924


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Detail - In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbruggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods. The compact form and clear structure of this monograph make this a long-awaited ready reference. From the contents: Introduction * Techniques of Preparative Silylations-Desilylations * Preparation and Properties of Siliconoxy-Leaving Groups * Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide * Reactions of Aldehydes and Ketones * Reactions of Alcohols, Ethers and Epoxides * Reaction of N-O Systems * Reactions of S-O and Se-O Systems * Cyclizations and Ring Enlargements * Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions * Formation of Carbon-Phosphorous Double- and Triple Bonds * Reductions and Oxidations * Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds * Formation of Polymers

Comprehensive Organic Functional Group Transformations :

Organic compounds

Author - Alan R. Katritzky, Stanley M. Roberts, Otto Meth-Cohn, Charles Wayne Rees
Publisher - Elsevier
Pages - 1420
ISBN - 9780080423227


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Detail - This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.

Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis :

Technology & Engineering

Author - Philip L. Fuchs
Publisher - John Wiley & Sons
Pages - 816
ISBN - 1118636139


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Detail - Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database e-EROS. Another hot volume in the series Handbooks of Reagents for Organic Synthesis, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key synthetic approaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization. 2. The specific use of the silane functionality as a hetero t-butyl group, often colloquially referred to as the use of silicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relay stratagem'. A new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.

Comprehensive Organic Functional Group Transformations II : A Comprehensive Review of the Synthetic Literature 1995 - 2003

Science

Author -
Publisher - Elsevier
Pages - 6400
ISBN - 0080523471


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Detail - Comprehensive Organic Functional Group Transformations II (COFGT-II) will provide the first point of entry to the literature for all scientists interested in chemical transformations. Presenting the vast subject of organic synthesis in terms of the introduction and interconversion of all known functional groups, COFGT-II provides a unique information source documenting all methods of efficiently performing a particular transformation. Organised by the functional group formed, COFGT-II consists of 144 specialist reviews, written by leading scientists who evaluate and summarise the methods available for each functional group transformation. Also available online via ScienceDirect – featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. By systematically treating each functional group in turn the work also identifies what is not known, thus pointing the way to new research areas Follows the systematic layout of the successful 1995 COFGT reference work, based on the arrangement and bonding of hetero-atoms around a central carbon atom The work will save researchers valuable time in their research as each chapter is written by experts who have critically read and reviewed the literature and presented the best methods of forming every known functional group

Application of Palladium Nanoparticles in the Reduction of Organic Functional Groups :

Halogenation

Author - Ronald James Rahaim
Publisher -
Pages - 412
ISBN -


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The British National Bibliography :

English literature

Author - Arthur James Wells
Publisher -
Pages -
ISBN -


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Books in Print 2009-2010 :

Publishers' catalogs

Author -
Publisher -
Pages -
ISBN - 9780835250214


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Metathesis in Natural Product Synthesis : Strategies, Substrates and Catalysts

Science

Author - Janine Cossy, Stellios Arseniyadis, Christophe Meyer
Publisher - John Wiley & Sons
Pages - 412
ISBN - 3527642080


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Detail - Emphasizing the impact of metathesis in natural product synthesis through the different types of key reactions, this is a comprehensive view of a hot topic. Written by top international authors, this ready reference is clearly structured and packed with important information, including representative experimental procedures for practical applications. A real must-have for anyone working in natural product synthesis.

Comprehensive organic functional group transformations II :

Science

Author - Alan R. Katritzky, Richard J. K. Taylor
Publisher -
Pages - 6400
ISBN - 9780080442563


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Detail - COFGT-II provides the first point of entry to the literature for all scientists interested in chemical transformations. Presenting the vast subject of organic synthesis in terms of the introduction and interconversion of all known functional groups, COFGT-II provides a unique information source documenting all methods of efficiently performing a particular transformation. Organized by the functional group formed, COFGT-II consists of 144 specialist reviews, written by leading scientists who evaluate and summarize the methods available for each functional group transformation.

Comprehensive organic functional group transformations II. : Carbon with two heteroatoms with at least one carbon-to-heteroatom multiple link

Science

Author - Alan Roy Katritzky, Richard J. K. Taylor, Ray C. F. Jones
Publisher -
Pages - 1138
ISBN - 9780080442563


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Comprehensive Organic Functional Group Transformations 2: Carbon with three or four attached heteroatoms :

Organic compounds

Author -
Publisher -
Pages - 765
ISBN - 9780080442587


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Silicon in Organic Synthesis : Butterworths Monographs in Chemistry and Chemical Engineering

Science

Author - Ernest W. Colvin
Publisher - Butterworth-Heinemann
Pages - 360
ISBN - 148314223X


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Detail - Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of α-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.